Thermally stable autonomic healing in epoxy using a dual-microcapsule system.

نویسندگان

  • Henghua Jin
  • Chris L Mangun
  • Anthony S Griffin
  • Jeffrey S Moore
  • Nancy R Sottos
  • Scott R White
چکیده

Self-healing is achieved with a dual-microcapsule system utilizing epoxy-amine chemistry in a high temperature cured thermosetting epoxy polymer. One capsule contains a modified aliphatic polyamine prepared by vacuum infiltration of polyoxypropylenetriamine into hollow polymeric microcapsules. The second capsule contains a difunctional epoxide and reactive diluent. Healing efficiency is accessed through recovery of fracture toughness and excellent long-term stability at ambient conditions is demonstrated.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Microcapsule-Type Self-Healing Protective Coating for Cementitious Composites with Secondary Crack Preventing Ability

A microcapsule-type self-healing protective coating with secondary crack preventing capability has been developed using a silanol-terminated polydimethylsiloxane (STP)/dibutyltin dilaurate (DD) healing agent. STP undergoes condensation reaction in the presence of DD to give a viscoelastic substance. STP- and DD-containing microcapsules were prepared by in-situ polymerization and interfacial pol...

متن کامل

Self-healing thermoset using encapsulated epoxy-amine healing chemistry

Self-healing was achieved with a dual-microcapsule epoxy-amine chemistry in thermoset epoxy. One capsule contained a modified aliphatic polyamine (EPIKURE 3274) while the second capsule contained a diluted epoxy monomer (EPON 815C). Amine microcapsules were prepared by vacuum infiltration of EPIKURE 3274 into hollow polymeric microcapsules. Epoxy microcapsules were prepared by an in situ polyme...

متن کامل

Evaluation of a Microcapsule Based Self-healing System for Cementitious Materials

An international cooperation research project has been financially supported by China Nature Science Foundation, which consists of three relatively independent, but strategically integrated research sub-programs, aiming at the formation of a selfhealing system based on the microcapsule principle for the cementitious composites. In this paper, a self-healing system triggered by physical process ...

متن کامل

A cyanate ester/microcapsule system with low cure temperature and self-healing capacity

A cyanate ester/microcapsule system with low cure temperature and self-healing " Abstract: Microcapsules filled with epoxy resin were blended into cyanate ester resin to produce systems with low cure temperature and self-healing capacity. A 4,4′-diaminodiphenylsulfone (DDS) curing agent was adopted for the systems. The mechanical properties, thermal stability and self-healing ability of the sys...

متن کامل

Preparation and Properties of Melamine Urea-Formaldehyde Microcapsules for Self-Healing of Cementitious Materials

Self-healing microcapsules were synthesized by in situ polymerization with a melamine urea-formaldehyde resin shell and an epoxy resin adhesive. The effects of the key factors, i.e., core-wall ratio, reaction temperature, pH and stirring rate, were investigated by characterizing microcapsule morphology, shell thickness, particle size distribution, mechanical properties and chemical nature. Micr...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:
  • Advanced materials

دوره 26 2  شماره 

صفحات  -

تاریخ انتشار 2014